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MULTIPHASE THERMODYNAMICS

Pure species phase equilibrium: Introduction, Criterion For Equilibrium, Pure Species Phase Equilibrium, Pure Species Chemical Potential, Pure Species Gibbs Energy Relation, Pressure Dependence of Pure Species Chemical Potential, PURE SPECIES FUGACITY, Fugacity as a Criterion for Pure Species Phase Equilibrium, Fugacity using Residual Volume, Fugacity using Compressibility Factors, Compressibility Factor Charts, Fugacity using Charts, Fugacity of Pure Saturated Liquids, Fugacity of Compressed Liquid States, Fugacity Coefficient using Cubic EOS, VLE for non-polar mixtures: The Apportioning Rule, the Recombination Rule and Gibbs-Duhem, Criteria For Phase Equilibrium, Gibbs Free Energy of a Mixture, Dalton’s Law, Fugacity Coefficient of a Component in a Mixture, Ideal Solutions and Lewis-Randall Rule, Criterion for Multicomponent Phase Equilibrium, Fugacity as a Criterion for Mixture Phase Equilibrium, Finding Fugacity Coefficient of a Component in a Mixture, VLE for non-polar systems, Rigorous Phi-Phi Approach to VLE, Liquid and Vapour as Ideal Solutions, Raoult’s Law: Liquid as an Ideal Solution and Vapour as an Ideal Gas, Phi-Phi VLE Summary, Finding K-Values using Charts, Vapour Pressure Correlation, Temperature-Composition Diagram for Binary System, Significance of K-Values, phase equilibrium calculations, Bubble Point Calculations, Dew Point Calculations,  Flash Calculations, VLE for polar liquid mixtures: Models Of Ideality And Standard States, Lewis-Randall Model of Ideality, Henry’s Law Model of Ideality, real mixtures, Excess Properties, Activity Coefficients, the gamma-phi approach to vle, Rigorous Gamma-Phi Approach to VLE, Vapour Phase as an Ideal Solution, Vapour Phase as an Ideal Gas, Both Phases as Ideal Solutions, Raoult’s Law, phase equilibrium diagrams, P-x-y Diagrams, T-x-y Diagrams,  The x-y Diagram, models of solution behaviour, The One Parameter Model, Margule’s Two Parameter Model, Van Laar’s Two Parameter Model, Wilson’s Local Composition Model, Real Mixtures, Property Changes on Mixing, Property Changes on Mixing for Ideal Solutions, Activity of a Species in a Mixture, Excess Properties, Positive & Negative Deviation from Ideality, Formation of Azeotropes, Vapour-Liquid Equilibrium, Liquid-Liquid Equilibrium and Miscibility, pure species, P-T Diagrams, P-v Diagrams, BINARY systems and miscible VLE, P-T Diagrams, P-x-y Diagrams, T-x-y Diagrams, x-y Diagrams, Azeotropes, partially miscible systems, Liquid-Liquid Solubility Diagrams, VLLE and P-x-y Diagram, VLLE and T-x-y Diagram, VLLE at Higher Temperature, Quantitative Treatment of VLLE, immiscible systems, Quantitative Treatment, Rigorous Approach to LLE, Liquid-Liquid Equilibrium, Heating or Cooling a VLLE System, Isobaric Cooling from “A”, Isobaric Cooling from “B”, Isobaric Cooling from “C”, Isobaric Vaporisation from “X”, Chemical equilibrium, reaction stoichiometry, Extent of Reaction,  equilibrium criterion, Equilibrium Constant, Approximate Temperature Dependence of K, Accurate Temperature Dependence of K, gas phase chemical equilibrium, Rigorous Non-Ideal Mixture, Ideal Solution Mixture, Ideal Gas Mixture, Effect of Pressure on Chemical Equilibrium, Calculation of Equilibrium Conversion, liquid phase chemical equilibrium, Rigorous Non-Ideal Mixture, Ideal Solution Mixture, heterogeneous reactions, Heterogeneous Reactions with Solids, Volumetric behaviour of real fluids and solids, P-T Diagram, P-v Diagrams, Relation between P-T & P-v Diagrams, volume expansivity and isothermal compressibility, Liquids and Solids, Gases, Reversible Volume Work, compressibility factor, Two-Parameter Generalised Correlations, Three-Parameter Generalised Correlations, virial EOS, Truncated Virial EOS,  second virial coefficient “B”, Experimental Determination, Generalised Correlations, cubic EOS, Manual Iteration Schemes, Generalised Correlations for Cubic Parameters, RKS EOS in Cubic Form.